Alkyl 2-aryl-2,2-dialkoxyacetates, the preparation thereof and a

Details Alkyl 2-aryl-2,2-dialkoxyacetates, the preparation thereof and a Alkyl 2-aryl-2,2-dialkoxyacetates, the preparation thereof and a

1992-07-02

1993-09-07

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 6976

Patent

active

052430669

ABSTRACT:
Alkyl 2-aryl-2,2-dialkoxyacetates are prepared by electrochemical oxidation of alkyl 2-arylacetates and are used to prepare arylglyoxylic esters.

REFERENCES:
Tetrahedron Letters, vol. 21, pp. 4997-5000 (by John M. Domagala), "A mild, rapid, and convenient esterfication of .alpha.-keto acids".
Liebigs Ann. Chem. 1980, 1271-1282, "Oxidation von 1,3-diphenyl-1,3-propandionen mit Thallium (III)-nitrat in Methanol".
Synthesis, 1983, pp. 203-205, "A Simple Procedure for the Acetalization of Carbonyl Compounds" by Chan, Brook & Chaly.

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