Alkoxylation process catalyzed by phosphate salts of the rare ea

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568608, 568620, 568 45, 568 55, 568678, 568679, 2604106, 560 93, 560201, 560200, 560105, 560112, 560240, 564399, 564475, 564505, 530217, 530230, 530232, C07C 4103

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active

050576275

ABSTRACT:
Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more of the phosphate salts of the rare earth elements. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.

REFERENCES:
patent: 4528364 (1985-07-01), Prier
patent: 4658065 (1987-04-01), Aoshima et al.
Y. Zhang, Inorganica Chemica Acta, 155 (1989) 263-265.

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