Alkoxylation process catalyzed by lanthanum silicates and metasi

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568 39, 568 45, 568608, 568620, 568622, 568678, 568679, 560263, 560265, 560200, 560240, 560 93, 560209, 560105, 560112, 564399, 564475, 564505, 2604106, 530217, 530232, L07L 4103

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049609521

ABSTRACT:
Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more lanthanum compounds comprising silicate, metasilicate and mixtures thereof. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.

REFERENCES:
patent: 4528364 (1985-07-01), Prier
patent: 4658065 (1987-04-01), Aoshima et al.
patent: 4665236 (1987-05-01), Edwards
Y. Zhang, "Ring Opening Polymerization of Ethylene Oxide by the Y(P.sub.204).sub.3 --Al(i--Bu).sub.3 --H.sub.2 O Catalyst", Inorganica Chemica Acta, 155 (1989), 263-265.

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