Alkoxylation process catalyzed by borate salts of the rare earth

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568608, 568620, 568 45, 568 55, 568678, 568679, 2604106, 560 43, 560209, 560200, 560105, 560112, 560240, 564399, 564475, 564505, 530217, 530230, 530232, C07C 4103

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050269232

ABSTRACT:
Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of one or more of the borate salts of the rare earth elements. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.

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patent: 4665236 (1987-05-01), Edwards
Y. Zhang, "Ring Opening Polymerization of Ethylene Oxide by the Y(P.sub.204).sub.3 --Al(i-Bu).sub.3 -H.sub.2 O Catalyst", Inorganica Chemica Acta, 155 (1989) 263-265.
Medvedeva, et al, "Saturated Polyesters", The American Chemical Society, vol. 86, p. 5988, 1977 (Abstract) Chem. Abs.
E. J. Rosenbaum, "Isomorphism of Borates and Carbonates", Chemical Abstracts, vol. 26, p. 4990, (Abstract).
N. N. Greenwood, "Borates", Comprehensive Inorganic Chemistry, pp. 888-889.

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