Alkoxylation of cresylic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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568315, 568608, 568609, 568610, 568584, 568586, 568426, 564170, 564413, 564443, 560 71, 546134, C07C 5100, C07C 4103

Patent

active

043768687

ABSTRACT:
Cresylic acid ethoxylation is catalyzed by basic compounds and salts of alkaline earth metals. Ethoxylates from such reactions have narrow ethylene oxide distributions, lower pour points and lower by-products as compared to alkali base catalyzed ethoxylation. Suitable catalysts include strontium-containing and barium-containing materials. The catalyst also includes co-catalyst combinations using these materials with one or more promoters including polyols, amines, amides, carboxylic acids and phenols. The co-catalyst combinations can be preformed prior to introduction into the reaction mixture.

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patent: 3297783 (1967-01-01), Bailey
patent: 3417064 (1968-12-01), Bailey
patent: 3830850 (1974-08-01), Stratton
patent: 4210764 (1980-07-01), Yang et al.
patent: 4223164 (1980-09-01), Yang et al.

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