Alkoxycarbonylation process

Details Alkoxycarbonylation process Alkoxycarbonylation process

1990-10-02

1992-02-11

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

502155, 502213, 560100, 560103, 562406, C07C 6736

Patent

active

050877313

ABSTRACT:
A process of alkoxycarbonylation making use of a new catalyst consisting of a palladium-phosphine complex, the phosphine having a pKa greater than or equal to 7, a chlorinated aromatic compound, carbon monoxide and an alcohol.

REFERENCES:
patent: 3988358 (1976-10-01), Heck
Henderson, Jr. et al., Journal of the American Chemical Society, 82, pp. 5791-5794 (1960).
Tolman, Journal of the American Chemical Society, 92, pp. 2956-2965 (1970).

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