Alkoxides of 2-pinanol

Chemistry of hydrocarbon compounds – Alicyclic compound synthesis – From nonhydrocarbon

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560174, 585363, 585375, 585378, 585379, C07C 1253

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active

042899176

ABSTRACT:
Alkali metal oxides of cis- and trans-2,6,6-trimethylbicyclo(3.1.1)-heptan-2-ol are surprisingly effective bases in organic reactions calling for the use of a strong base, especially those reactions wherein abstraction of a proton from attachment to a carbon atom is postulated to occur in the mechanism.

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patent: 3399244 (1968-08-01), Qut et al.
patent: 4136126 (1979-01-01), Hirschy et al.
J. R. Salmon et al., J. Chem. Soc. (B), p. 1249, 1971.
W. D. Burrows et al., J. Amer. Chem. Soc. 81, p. 245, 1958.

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