Alkenylation catalysts

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 300

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active

040340520

ABSTRACT:
Unsaturated amines, primary and secondary saturated amines, N,N,N',N'-tetramethylethylenediamine, N,N,N',N'-tetramethyl-1,3-propanediamine, and ammonia cocatalysis with alkali metals for alkenylation of alkylaromatics having benzylic hydrogen with conjugated diolefins of 4-15 carbon atoms. Improved trans:cis product ratio and improved yield are produced by these nitrogen containing cocatalysts.

REFERENCES:
patent: 1934123 (1933-11-01), Hofmann et al.
patent: 2994725 (1961-08-01), Shaw et al.
patent: 3028441 (1962-04-01), Bush et al.
patent: 3244758 (1966-04-01), Eberhardt
patent: 3766288 (1973-10-01), Shima et al.

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