Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1992-09-28
1994-08-30
Shippen, Michael L.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
C07C 6705
Patent
active
053429877
ABSTRACT:
This invention provides a process for producing improved catalysts for the production of alkenyl alkanoates by the reaction of an alkene, an alkanoic acid and an oxygen-containing gas. The catalysts contain palladium, gold and a potassium promoter and are characterized by a reduced sodium content which results in increased catalyst activity. The reduced sodium content is obtained by washing the catalyst, at a particular intermediate point in its production, with a cation exchange solution.
REFERENCES:
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patent: 4048096 (1977-09-01), Bissot
patent: 4087622 (1978-05-01), Nakamura et al.
Journal of Catalysis, vol. 17, pp. 366-374, 1970 (Nakamura et al.).
Chemical Abstracts vol. 115(14):136969y (1991).
Chemical Abstracts vol. 70(9):37210q (1969).
Chemical Abstracts vol. 75(14):89050k (1971).
Shippen Michael L.
Trautlein E. C.
Union Carbide Chemicals & Plastics Technology Corporation
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