Alkenol synthesis

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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260467, C07C 2960, C07C 7702

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active

044005628

ABSTRACT:
3-Buten-1-ol is synthesized from 1,3-butanediol by heating a polyol in the resence of a trivalent metal sulfate to a temperature from about 70.degree. C. below to about 100.degree. C. above the boiling point of 1,3-butanediol.

REFERENCES:
patent: 2422802 (1947-06-01), Schelling et al.
patent: 3001975 (1961-09-01), Beavers et al.
patent: 3636167 (1972-01-01), Tedeschi et al.
Traynelis et al., J. Org. Chem. 27, pp. 123-128 (1962).
Malcolm E. Winfield, J. Council Sci. Ind. Res. 18, pp. 412-423 (1945).

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