Alkenol production

Details Alkenol production Alkenol production

1974-06-28

1976-06-01

Evans, Joseph E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260453R, 2604656, 260484R, 260488H, 260615R, 260617R, 260618R, 260633, 260681, C07C 2900

Patent

active

039609731

ABSTRACT:
The yield of alkenols is substantially improved by carrying out the reaction of olefins with formaldehyde in the presence of selected catalysts. In accordance with one embodiment, alk-3-en-1-ols are produced in good yields from isobutylene and formaldehyde in the presence of selected catalysts comprising compounds of Group IB metals, Group VIB metals, Group VB metals, Group VIIB metals, Group III metals, alkali metal, and alkaline earth metals, and fluorided alumina.

REFERENCES:
patent: 2308192 (1943-01-01), Mikeska et al.
patent: 3081357 (1963-03-01), Alderson et al.
patent: 3414588 (1968-12-01), Jones
patent: 3706809 (1972-12-01), Moroe et al.
patent: 3818043 (1974-06-01), Starks
Arundale et al. "Chem. Rev." vol. 51, No. 3 (1952), pp. 505-555.

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