Alkene separation process

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By dehydrogenation

Reexamination Certificate

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C585S324000, C585S809000, C585S843000, C585S844000, C585S845000, C585S848000, C585S850000, C585S856000, C560S241000, C560S214000, C560S243000, C560S245000, C562S548000, C562S549000, C562S606000

Reexamination Certificate

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07411107

ABSTRACT:
A process for the oxidation of a C2to C4alkane to produce the corresponding alkene and carboxylic acid which process comprises separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solution, and recovery of an alkene-rich stream from the metallic salt solution. Integrated processes for the production of alkyl carboxylate and alkenyl carboxylate, which processes comprise oxidation of a C2to C4alkane to produce the corresponding alkene and carboxylic acid, separation of the alkene from a mixture of the alkene, the alkane and oxygen by absorption in a metallic salt solution, and recovery of an alkene-rich stream from the metallic salt solution for use in production of alkyl carboxylate or alkenyl carboxylate.

REFERENCES:
patent: 6040474 (2000-03-01), Jobson et al.
patent: 6143921 (2000-11-01), Karim et al.
patent: 6476261 (2002-11-01), Ellis et al.
patent: 6518476 (2003-02-01), Culp et al.
patent: 0 985 656 (2000-03-01), None
patent: WO 00/37399 (2000-06-01), None
patent: WO 01/90042 (2001-11-01), None
patent: WO 01/90043 (2001-11-01), None

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