Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1997-03-11
1999-08-10
Owens, Amelia
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
556482, 558210, C07C 4302, C07F 704, C07F 902
Patent
active
059361328
ABSTRACT:
A chemiluminescent 1,2-dioxetane derivative having a formula (I): ##STR1## wherein R.sup.1 and R.sup.4 each represent, individually, hydrogen, an alkyl group, an alkoxyl group, a hydroxyl group, or --OS;(R.sup.9 R.sup.10 R.sup.11) in which R.sup.9, R.sup.10 and R.sup.11 each represent an alkyl group; R.sup.2, R.sup.3, R.sup.5 and R.sup.6 each represent, individually, hydrogen or an alkyl group, provided that R.sup.2, R.sup.3, R.sup.5 and R.sup.6 each cannot be hydrogen at the same time, and that R.sup.2 and R.sup.3, and R.sup.5 and R.sup.6, each taken together, can form a cycloalkyl group; R.sup.7 represents an alkyl group; R.sup.8 represents hydrogen, an alkoxyl group, a phosphate salt group, or --OSi(R.sup.9 R.sup.10 R.sup.11); intermediates for synthesizing the above 1,2-dioxetane derivative; and methods of producing the intermediates are provided.
REFERENCES:
Journal of Heterocyclic Chemistry, vol. 14, No. 2, Apr. 1997, PROVO US pp. 181-184.
Journal of the Chemical Society, Chemical Communications, vol. 21, Nov. 7, 1994, Letchworth GB pp. 2449-2450.
Matsumoto, M. et al "Thetmal stability and chemiluminescence of 3-alkoxy-3-aryl-4,4-diisopropyl-1,2-dioxetanes" CA 122:313997, 1995.
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