Alkene coupling

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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C07C 224

Patent

active

049820443

ABSTRACT:
A normal 1-alkene containing 3-8 carbons is coupled with itself, another such alkene, or ethene in the presence of a supported alkali metal as a catalyst and about 10-100 mol %, based on the amount of alkali metal catalyst, of an alkali metal hydroxide as a co-catalyst; the support being a silica having a surface area not greater than 5 m.sup.2 /g. In preferred embodiments of the invention, the alkene is propene or a mixture of propene and ethene, the alkali metal is potassium or a potassium alloy, and the co-catalyst is potassium hydroxide.

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