Alkanediyl bridged benzimidazolo monomethine cyanine dyes, proce

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430570, 430583, G03C 102

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active

044904630

ABSTRACT:
Alkanediyl bridged benzimidazolo monomethine cyanine dyes are disclosed wherein at least one benzimidazolo nucleus is provided with an electron-withdrawing group. A disclosed preparation of the dyes includes producing an electron-withdrawing group substituted bis(2-nitrophenyl)-2-R.sup.1 -propanediamide, where R.sup.1 is hydrogen or alkyl; converting the nitro groups to primary amine substituents; removing the elements of water to effect ring closure; and thereafter providing the -CR.sup.1 - linked benzimidazole nuclei so formed with an N,N'-alkanediyl bridging group and quaternizing substituents. Dye synthesis is completed by reducing the -CR.sup.1 - linking group to the corresponding methine. The dyes are useful as sensitizers in silver halide emulsions and photographic elements.

REFERENCES:
patent: 2479152 (1949-08-01), Brooker
patent: 2541400 (1951-02-01), Brooker et al.
patent: 3337578 (1967-08-01), Bader et al.
patent: 3622317 (1971-11-01), Bird et al.
patent: 3904637 (1975-09-01), Lincoln et al.

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