Alkane isomerization using reversible flow

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By isomerization

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585734, 585739, 585744, 585750, 585751, C07C 513

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active

06118036&

ABSTRACT:
A process to isomerize at least one normal or mono-methyl-branched alkane to form at least one multi-methyl-branched alkane has been developed. At least one normal or mono-methyl-branched is introduced to a reaction zone to form at least one multi-methyl-branched alkane. The reaction zone is located between a first and a second adsorption zone with the adsorption zones containing an adsorbent effective to selectively adsorb normal and mono-methyl-branched alkanes relative to multi-methyl-branched alkanes. A desorbent is introduced to the first adsorption zone and an effluent containing at least one multi-methyl-branched alkane is withdrawn from the second adsorption zone. After a period of time, the introduction of the desorbent is redirected to the second adsorption zone and concurrently the withdrawal of the effluent is moved to the first adsorption zone.

REFERENCES:
patent: 4783574 (1988-11-01), Barnes
patent: 5744684 (1998-04-01), Zinnen et al.

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