Alkane acetates produced by oxidative esterification of olefins

Details Alkane acetates produced by oxidative esterification of olefins Alkane acetates produced by oxidative esterification of olefins

1982-07-28

1984-05-22

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 6705

Patent

active

044502907

ABSTRACT:
A process for the production of alkane acetates from olefins in the presence of a transition metal borate catalyst, oxygen and acetic acid alone via oxidative esterification is described. The reaction is conducted at a temperature in the range of 120.degree. to 220.degree. C. and a pressure of 1 atmosphere or greater. Alkane diacetates and hydroxy acetates are produced which may be used as precursors to alkylene oxides, alkylene glycols and other useful compounds.

REFERENCES:
patent: 3981908 (1976-09-01), Ganzler
patent: 4220800 (1980-09-01), Stapp

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