Alkane acetates produced by oxidative esterification of olefins

Details Alkane acetates produced by oxidative esterification of olefins Alkane acetates produced by oxidative esterification of olefins

1982-07-28

1984-03-13

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 6705

Patent

active

044369310

ABSTRACT:
A process for the production of alkane acetates from olefins in the presence of an oxide catalyst selected from the group of oxides consisting of niobium oxide, iron oxide and bismuth oxide, oxygen and a carboxylate ion source via oxidative esterification is described. The reaction is conducted at a temperature in the range of 100.degree. to 250.degree. C. and a pressure of 1 atmosphere or greater. Iron oxide catalysts are preferred. Alkane diacetates and hydroxy acetates are produced which may be used as precursors to alkylene oxides, alkylene glycols and other useful compounds.

REFERENCES:
patent: 4208534 (1980-06-01), Murib
patent: 4238624 (1980-12-01), Morris

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