Alkane acetates produced by oxidative esterification of olefins

Details Alkane acetates produced by oxidative esterification of olefins Alkane acetates produced by oxidative esterification of olefins

1982-07-28

1984-03-13

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560243, 502202, C07C 6705, C07C 67055

Patent

active

044369280

ABSTRACT:
A process for the production of alkane acetates from olefins in the presence of an oxide/borate catalyst system, oxygen and a carboxylate ion source via oxidative esterification is described. The reaction is conducted at a temperature in the range of 100.degree. to 250.degree. C. and a pressure of 1 atmosphere or greater. Alkane diacetates and hydroxy acetates are produced which may be used as precursors to alkylene oxides, alkylene glycols and other useful compounds.

REFERENCES:
patent: 3393225 (1968-07-01), Fenton
patent: 3470230 (1969-09-01), Hirsch
patent: 3652668 (1972-03-01), Bryce-Smith
patent: 3657292 (1972-04-01), Parshall
patent: 4113971 (1978-09-01), Stapp
patent: 4220800 (1980-09-01), Stapp

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