Alkaline earth metal compound-supported silver catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502208, 502224, 502226, 502227, 502228, 502231, 502341, 502344, 502347, 502348, B01J 2350, B01J 2718, B01J 27135

Patent

active

060838701

ABSTRACT:
Propylene is oxidized to propylene oxide in the vapor phase using an oxygen-containing gas and a supported silver catalyst comprising silver and a support comprised in whole or in substantial part of certain alkaline earth metal compounds. The alkaline earth metal compound may, for example, be a calcium compound such as calcium titanate, tribasic calcium phosphate, calcium molybdate, or calcium fluoride, a magnesium compound such as magnesium aluminate, or a strontium compound such as strontium titanate. Such supports provide significantly higher selectivity to the desired epoxide than would be expected from the performance of related materials. Propylene oxide selectivity may be further enhanced through the introduction of nitrogen oxide species such as NO, alkyl halides such as ethyl chloride, and carbon dioxide into the oxygen-containing gas.

REFERENCES:
patent: 4410715 (1983-10-01), McMullin et al.
patent: 5145824 (1992-09-01), Buffum et al.
patent: 5502020 (1996-03-01), Iwakura et al.
patent: 5504053 (1996-04-01), Chou et al.
patent: 5686380 (1997-11-01), Pitchai et al.

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