Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1973-08-23
1976-09-28
Demers, Arthur P.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
2604482E, 2604482R, 260666P, 260668R, 260676R, 260677R, 423439, C07F 102, C07F 104, C07F 100
Patent
active
039831825
ABSTRACT:
Alkali metal organic compounds including perlithiated organic compounds are produced by contacting an organic compound having a carbon to hydrogen bond or a carbon to halogen bond in its molecular structure or carbon vapor with a vaporous alkali metal under dry conditions and in the absence of a gas that reacts with the alkali metal other than the organic compound. The alkali metal is activated such as thermally or by being passed through a radio frequency field so that it has sufficient energy to break at least one of the bonds. Perlithiated compounds are formed from alkanes, alkenes, cycloalkanes and aromatic hydrocarbons.
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Cook Paul J.
Demers Arthur P.
Massachusetts Institute of Technology
Santa Martin M.
Smith, Jr. Arthur A.
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