Alkali activated class C fly ash cement

Compositions: coating or plastic – Coating or plastic compositions – Inorganic settable ingredient containing

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106708, 106707, 106DIG1, 106697, 588257, C04B 712, C04B 736

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active

055650287

ABSTRACT:
Class C fly ash may be activated with strong alkali to yield a novel, dense, quick-setting cement having unexpected properties. The setting time of the cement decreased as the pH of the activating solution increased. The microstructure and phase assemblage of the novel cement depended on the pH. Ettringite was absent beyond pH 14.30 (2.0N); a hexagonal plate-like crystalline form (stratlingite (gehlenite hydrate, C.sub.2 ASH.sub.8) and other compounds) became more abundant at higher pH. At higher pH the microstructure was characterized by high amounts of the plate-like crystalline phase and a dense matrix, due to higher reactivity of the glassy phase in fly ash. The novel cement will have uses in a number of areas, including fixation of hazardous wastes such as radioactive wastes, applications where rapid setting is desired, and formation of concrete in hot environments where ordinary Portland cements may tend to crack due to their heat of hydration.

REFERENCES:
patent: 3854968 (1974-12-01), Minnick et al.
patent: 4050950 (1977-09-01), Brewer et al.
patent: 4226030 (1980-10-01), Styron
patent: 4313763 (1982-02-01), Turpin, Jr.
patent: 4353749 (1982-10-01), Ray et al.
patent: 4374672 (1983-02-01), Funston et al.
patent: 4375986 (1983-03-01), Pichat
patent: 4642137 (1987-02-01), Heitzmann et al.
patent: 4715896 (1987-12-01), Berry
patent: 4761182 (1988-08-01), Whitescarver et al.
patent: 4997484 (1991-03-01), Gravitt et al.
patent: 5073198 (1991-12-01), Kurz
patent: 5288321 (1994-02-01), Davidovits
patent: 5366547 (1994-11-01), Brabston et al.
patent: 5372640 (1994-12-01), Schwarz et al.
patent: 5435843 (1995-07-01), Roy et al.
E. Rau, "The Poz-O-Tec Process for Fixation of Industrial Waste," Proc. VII.sup.th Int. Cong. Chem. Cem., Paris, pp. 657-662 (1980) (no month).
P. Schilling, "The Structure of Cementitious Materials Produced by Alkali Activation of Calcium Aluminosilicate Glasses," PhD Dissertation, Louisiana State University (defended 1992; catalogued and shelved 1993). (no month).
W. H. Buttermore, "The Use of Pulverized Coal Flyash and Limestone Fluid Bed Combustor Ash in the Production of Lightweight Cellular Concrete," in M. D. LaGrega et al. (eds.), Toxic and Hazardous Wastes, Proc. 16.sup.th Mid-Atlantic Indst. Waste Conf., pp. 230-240 (1984) (no month).
V. D. Glukhovsky et al., "High-strength Slag-Alkaline Cements," Proc. VII.sup.th Int. Cong. Chem. Cem., V, pp. 164-168 (1980) (no month).
M. Kawamura et al., "Reaction Process and Microstructure in Compacted Fly Ashes and Fly Ash-Chemical Additive Mixtures," Proc. VIII.sup.th Int. Cong. Chem. Cem., Rio de Janeiro, 3.1, 92-97 (1986) (no month).
A. L. A. Fraay et al., "The Reaction of Fly ash in Concrete. A Critical Examination," Cem. Concr. Res., vol. 19, pp. 235-246 (1989) (no month).
A. Roy et al., "Solidification/Stabilization of Hazardous Wastes: Evidence of Physical Encapsulation," Environ. Sci. & Technol., vol. 26, pp. 1349-1353 (1992) (no month).
A. Roy et al., "Activation of Ground Blast-Furnace Slag by Alkali-Metal and Alkaline Earth Hydroxides," J. Am. Ceram. Soc., vol. 75, No. 12, pp. 3233-3240 (1992) (no month).
A. Roy et al., "Alkali Activation of Class C Fly Ash," Proc. ASCE Natl. Conv. New York (Sep. 13-17, 1992).
S. J. Way et al., "Early Hydration of a Portland Cement in Water and Sodium Hydroxide Solutions: Composition of Solutions and Nature of Solid Phases," Cement and Concrete Res., vol. 19, pp. 759-769 (1989) (no month).
R. Helmuth, Fly Ash in Cement and Concrete, Portland Cem. Assoc., pp. 1-17 (1987) (no month).
Kosmatka et al., "Design and Control of Concrete Mixtures," Thirteenth Ed., PCA, pp. 68-69 (1988) (no month).
J. MacDowell, "Hydrogarnet-Gehlenite Hydrate Cements from CaO-Al.sub.2 O.sub.3 -SiO.sub.2 Glasses," Int. Cong. Chem. Cem., Rio de Janiero, pp. 423-428 (1986) (no month).

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