Aliphatic polyester carbonate and process for producing the alip

Details Aliphatic polyester carbonate and process for producing the alip Aliphatic polyester carbonate and process for producing the alip

1997-07-28

1999-03-09

Short, Patricia A.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

528272, 528278, 528279, 528281, 528283, 528296, C08G 6364

Patent

active

058802240

ABSTRACT:
A process for producing an aliphatic polyester carbonate which comprises reacting (1) an aliphatic dicarboxylic acid compound containing succinic acid as a main component, (2) an aliphatic dihydroxy compound containing 1,4-butanediol as a main component, and (3) (a) a polyhydric alcohol having 3 or more hydroxyl groups in a molecule, (b) a polybasic carboxylic acid compound having 3 or more carboxyl groups in a molecule, or (c) a polybasic carboxylic acid having one or more hydroxyl groups in a molecule to obtain an aliphatic polyester oligomer and reacting the obtained aliphatic polyester oligomer and a carbonate compound, wherein the aliphatic polyester carbonate has a melt tension of 1.5 g or more at 190.degree. C. and at an extrusion rate of 10 mm/minute; a process for producing an aliphatic polyester carbonate which comprises reacting above components (1) and (2) to obtain an aliphatic polyester oligomer and reacting the obtained aliphatic polyester oligomer, above component (3) (a), and a carbonate compound, wherein the aliphatic polyester carbonate has the same properties; and aliphatic polyester carbonates produced by these processes. The aliphatic polyester carbonate is branched and biodegradable, has a high molecular weight, and shows higher melt tension and more excellent molding property in comparison with conventional linear aliphatic polyester carbonates in molding of the polyester carbonate to prepare films, sheets, fibers, and other molded products.

REFERENCES:
patent: 4533728 (1985-08-01), Waniczek
patent: 5654380 (1997-08-01), Kawai

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