Alicyclic ketoesters and process for their manufacture

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260464, 260514K, 260586R, 252522, C07C 6974

Patent

active

039548341

ABSTRACT:
New alicyclic ketoesters having the generic formula ##SPC1##
Wherein R represents a hydrocarbon radical containing from 4 to 8 carbon atoms, and R' represents an alkyl radical containing from 1 to 2 carbon atoms, are prepared, in one embodiment, by condensing the methyl or ethyl ester of propane-1,2,3-tricarboxylic acid with methyl or ethyl esters of 2-bromo acids containing from 6 to 10 carbon atoms, and hydrolyzing, decarboxylating and re-esterifying the resulting cyclic keto-triesters.
The new compounds have olfactory properties and are useful in the production of a great variety of perfumes.

REFERENCES:
patent: 3158644 (1964-11-01), Demele et al.

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