Alcohol carbonylation process using a bimetallic nickel catalyst

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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2604109R, 260413, 549295, 560 97, 560105, 560114, 560204, 560206, 560265, 562406, 562497, 562519, 568485, 568486, 568487, 568715, 568814, 568852, 568861, 568902, C07C 2932, C07C 3108, C07C 4549, C07C 5112, C07C 6736, C07C 3322

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active

046250492

ABSTRACT:
A process for the preparation of carboxylic acids, alcohols, aldehydes or the secondary products thereof which comprises reacting an alcohol having from one to about twenty carbon atoms with hydrogen and carbon monoxide in the presence of a heterogeneous sulfided catalyst comprising nickel in admixture with a co-catalyst selected from the elements of Groups V-B, VI-B and the Actinide series of the Periodic Table.

REFERENCES:
patent: 2593440 (1952-04-01), Hagemeyer
patent: 3285948 (1966-11-01), Butter
patent: 3387043 (1968-06-01), Kuraishi et al.
patent: 4304946 (1981-12-01), Isogai et al.
patent: 4431835 (1984-02-01), Gauthier-Lafaye et al.

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