Alcohol and aldehyde production using ruthenium carbonyl catalys

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568455, 568882, 568909, C07C 4550, C07C 2916

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active

043060846

ABSTRACT:
The present invention is an isomerically specific improvement of the oxo process reaction. It comprises the reaction of an olefin with carbon monoxide and water or hydrogen in a basic solution in the presence of a ruthenium carbonyl catalyst to preferentially produce the next higher normal aldehyde, or alcohol.

REFERENCES:
patent: 3020314 (1962-02-01), Alderson
patent: 3636159 (1972-01-01), Solomon
patent: 3929900 (1975-12-01), Schnur et al.
patent: 3933919 (1976-01-01), Wilkinson
patent: 3984478 (1976-10-01), Homeier
patent: 4098747 (1978-07-01), Haag et al.
patent: 4226845 (1980-10-01), Laine

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