Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component
Patent
1970-08-24
1977-03-29
Peters, G. O.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Sulfur or sulfur containing component
B01D 5334
Patent
active
040149781
ABSTRACT:
A system and method are described in which sulfur-containing flue gases are contacted with a solution containing excess calcium or magnesium bicarbonate. The sulfur oxides are reacted with the bicarbonate producing soluble bisulfites. This solution is then oxidized for pH control to produce calcium or magnesium sulfate and sulfuric acid. Dolomite or limestone or similar additives are then introduced to precipitate sulfates and to regenerate the bicarbonate solution for recycle to the scrubber.
REFERENCES:
patent: 2042477 (1936-06-01), Miller et al.
patent: 2080779 (1937-05-01), Lessing
patent: 2090143 (1937-08-01), Nonhebel et al.
patent: 2113198 (1938-04-01), Nonhebel et al.
Pearson, J. L., et al.; "A Dissertation on the Howden - I.C.I. Flue Gas Washing System," The Institute of Fuel; London; 1934; pp. 1, 12-16, 19-23.
Pascal, et al.; Nouveau Traite de Chimie Minerale, Vol. IV, pp. 416-417; Masson et Cie., Paris, 1958.
Bozzuto Carl R.
Klein Herschel A.
Berneike Richard H.
Combustion Engineering Inc.
Peters G. O.
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