Air activated organotin catalysts for polyurethane synthesis

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing

Reexamination Certificate

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C502S152000, C502S156000, C502S227000, C502S439000

Reexamination Certificate

active

07919423

ABSTRACT:
This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.

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Kosugi et al., Bull.Chem.Soc.Jpn., 60, 3462-3464(1987), in further view of Frances et al. (USP 5,075,468).
B. Jousseaume et al, Air Activated Organotin Catalysts for Silicone Curing and Polyurethane Preparation, Organometallics, 1994, pp. 1034-1038, vol. 13.
M. Kosugi et al., Preparation and Some Properties of Acyltin Compounds, Bull. Chem. Soc. JPN., 1987, p. 3462-3464, vol. 60.
Hostettler, F. et al, Organotin Compounds in Isocyanate Reactions, Ind. Eng. Chem, 1960, pp. 609-610, vol. 52.
Sawyer, A. K., Some Reactions of Organotin Hydrides With Organotin Oxides and Alkoxides, K. Am. Chem Soc., 1965, pp. 537-539, vol. 87.

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