Air-activated organotin catalysts for polyurethane synthesis

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

Reexamination Certificate

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C502S131000, C502S172000, C502S239000, C502S310000

Reexamination Certificate

active

07977446

ABSTRACT:
This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.

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F. Hostettler et. al., Organotin Compounds in Isocyanate Reactions, Ind. Eng. Chem., 1960, pp. 609-610, vol. 52.
Jousseaume et. al., Air Activated Organotin Catalysts for Silicone Curing and Polyurethane Preparation, Organometallics, 1994, pp. 1034-1038, , vol. 13.
T.N. Mitchell et. al., A Convenient Laboratory-Scale Preparation of Trimethylacyltins, Synthesis, 1990, pp. 1001-1002.
A.K. Sawyer et. al., Some Reactions of Organotin Hydrides With Organotin Oxides and Alkoxides, J. Am. Chem. Soc., 1965, pp. 537-539, vol. 87.

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