Aging resistance shape selective catalyst with enhanced activity

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

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208120, 208216R, 208251H, 208254H, 585671, 585739, C10G 1105, C10G 4720

Patent

active

044486731

ABSTRACT:
A shape selective catalyst useful in a variety of hydrocarbon conversion processes such as cracking, hydrocracking, hydrofining, isomerization, dewaxing, and the like, is obtained from the process which comprises steaming a precursor crystalline aluminosilicate in the hydrogen or ammonium form having a silica-alumina ratio greater than 12, a constraint index between about 1 and about 12 and an alpha value greater than about 20 in the presence of ammonia to provide a crystalline aluminosilicate having an alpha value of from about 10 to about 150 and thereafter ion-exchanging the steamed precursor with an alkali metal cation under conditions effective to further reduce the alpha value of the crystalline aluminosilicate to less than about 10.

REFERENCES:
patent: 3541027 (1970-11-01), Lapides
patent: 3755145 (1973-08-01), Orkin
patent: 4257872 (1981-03-01), La Pierre et al.
patent: 4263129 (1981-04-01), Chen et al.
patent: 4269697 (1981-05-01), Chen et al.
patent: 4315814 (1982-02-01), Shihabi

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