Aerosol hazard characterization and early warning network

Data processing: measuring – calibrating – or testing – Measurement system in a specific environment – Chemical analysis

Reexamination Certificate

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C702S023000, C702S026000

Reexamination Certificate

active

06490530

ABSTRACT:

The present invention is concerned with a method and apparatus for monitoring the progress and composition of a cloud of aerosol particles that had been released previously into the atmosphere. By “progress” is meant position and concentration relative to a region for which said aerosol cloud may pose a health hazard.
Expressly incorporated herein are the following patents concerning means and techniques by which such aerosol constituents of the cloud may be classified and/or identified:
4,548,500—“Process and Apparatus for Identifying or Characterizing Small Particles.” (Oct. 22, 1985).
4,693,602—“Method and Apparatus for Measuring the Light Scattering Properties of Small Particles.” (Sep. 15, 1987).
4,710,025—“Process for Characterizing Suspensions of Small Particles.” (Dec. 1, 1987).
BACKGROUND
Most of the aerosol particles present in the Earth's atmosphere pose little or no health hazard. Even the occasional dangerous aerosol particle is of negligible importance because its concentration is so low However, when pathologically hazardous aerosol particles occur in great numbers, their potential to cause illness or injury increases dramatically The presence of high concentrations of such aerosol particles can occur naturally or from man made sources. Volcanic eruptions are examples of the former while accidental chemical plant releases and refinery plant explosions are representative of the later.
Other natural releases of potentially dangerous aerosols include those occurring during the rapid formations of photochemical smogs, often initiated by manmade contributions such as automobile exhaust products. The natural releases of fungal spores, such as Coccidiodes immitis, the causative agents of coccidioses, under the occasional environmental conditions needed to promote the rapid growth and maturation of the parent fungi, can have devastating effects on the health of those affected. Finally, there is a large range of potentially lethal aerosols that might be released by terrorist or military groups intent on inflicting great numbers of casualties. These include aerosols of both biological and chemical origin and their release is generally expected to be surreptitious.
When dangerous aerosol particulate clouds occur within or adjacent to populated areas, it is desirable to provide an early warning for the inhabitants that might be affected were they to inhale such aerosols. Such warnings can result in a dramatic reduction of casualties in spite of the possible unpredictable collateral responses, such as civil unrest due to fear or panic, by the endangered population. It has often been reasoned that by the time such aerosol threats are detected and identified, it is too late to issue a warning to the potentially affected population. This is not generally true.
Aerosol intrusions often occur as dispersals in the form of clouds released above the ground. For example, volcanic eruptions generally send huge quantities of material into the upper atmosphere from which the aerosol particles fall back to the earth and only affect the local populations once they reach near ground levels. In ambient air, a particle of radius 10
−6
m=1 &mgr;m and density of 1 gm/cm
3
would require almost 3 hours to fall just one meter. Thus with a suitably deployed warning system, the threat posed by such aerosols will be ascertained long before they reach altitudes or locations where their presence might cause injury.
There are many types of aerosols that are hariless. Obvious examples are water droplets or even fine ice mists. It is important that any viable warning system be able to differentiate between potentially dangerous aerosols and the more common harmless varieties.
The means by which aerosol threats to a local population be recognized is an important object of this invention. Obviously, for volcanic eruptions or chemical plant explosions or similar aerosol intrusions, the source and location of the resultant aerosol cloud is easily noted and tracking is often straightforward, except perhaps at night if visual means are used. This type of daylight tracking is generally passive and based on the observation of the effect of such intrusive clouds upon background illumination. Knowing the source of the cloud means that its composition is also known, at least initially. Instrumentation may be brought into the affected regions for purposes of local compositional monitoring that, eventually, forms the basis for evacuation planning if needed. Additionally, once a potentially threatening aerosol cloud has been detected, its monitoring may be achieved to some degree by optical or radio wave probing of the cloud using laser or radio sources at a safe distance from the threat.
A popular concept for providing warning of an aerosol threat is based on a traditional RADAR approach using laser produced radiation to probe the cloud threat at a distance. NASA had applied such techniques in their extensive measurement programs of 1989 through 1990 as a means for the profiling of aerosol and cloud backscatter, Doppler wind measurements, and the measurement of atmospheric trace species. Despite exceedingly large Federal expenditures in this area, the technique is not expected to yield any practical optical signals capable of permitting cloud composition to be deduced. Nevertheless, for clouds of known origin, composition may be deduced based on such a priori information. Ulich et al. in their U.S. Pat. No. 5,257,085 discuss many elements and variations of this technique for probing the physical properties of distant scenes by use of both active and passive interrogations.
The LIDAR (light detection and ranging) technique has various faults including requirements for an unimpeded view of the aerosol, i. e. without intervening particulates, atmospheric interferences, or opaque structures. Inferring aerosol concentrations from such LIDAR measurements of unknown particles is unlikely. Mixed aerosol compositions as well as size distributions that are changing in time illustrate further shortcomings of the concept. Esproles, in his U.S. Pat. No. 5,345,168, has explored some novel means for improving the information content in the returned LIDAR signal. Min et al. in their U.S. Pat. No. 5,102,218 discuss LIDAR measurements at very short ranges, generally less than 30 meters, for extracting target signatures from mixtures of target components and naturally occurring aerosol particles. The referenced patent's detailed description includes many references to the target aerosol discrimination techniques used for so-called active optical proximity sensors together with extensive discussion of the then-current state-of-the-art.
Stewart et al. in their U.S. Pat. No. 4,687,337 discuss the need to deduce the extinction coefficients of aerosol particles by means of instrumentation taken to the various sites to be studied. Such so-called point source or in situ measurements are contrasted in their patent to the conventional LIDAR measurements. However, bringing instrumentation and personnel into regions thought to contain dangerous aerosol particles is usually avoided. For this reason, remote-sensing techniques for probing suspected targets have always been considered preferable. Carrieri in his U.S. Pat. No. 5,241,179 discusses this requirement in greater detail explaining the research programs of the U. S. Army Research, Development, and Engineering Center from the 1960s. The objective of these programs was the development of remote sensors “. . . for detecting threat chemical and biological agents in vapor cloud, aerosol, rain, and . . . ” as surface contaminants. A need for passive spectroscopic techniques was recognized in the early 1970s. Such techniques would collect and process radiance from natural or preexisting sources.
Advanced development on a remote chemical agent detection unit began in 1979. As of the filing of the Carrieri patent in late 1992, the differential scattering/differential absorption LIDAR devices, referred to simply as DISC/DIAL devices, were said to show the most promise and wer

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