Adsorption and isomerization of normal and mono-methyl paraffins

Chemistry of hydrocarbon compounds – Purification – separation – or recovery – By contact with solid sorbent

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Details

585737, 585738, 585739, 585821, 585825, C07C 713, C07C 7135

Patent

active

049565214

ABSTRACT:
This invention relates to processes for separating by adsorption lower octane normal and mono-methyl paraffins from hydrocarbon feeds containing normal, mono-methyl and more highly branched paraffin fractions and isomerizing the normal and mono-methyl paraffins to produce higher octane isopentane and more highly branched paraffins. Adsorbents capable of adsorbing both normal and mono-methyl paraffins are used either alone or in combination with adsorbents capable of adsorbing normal paraffins but not mono-methyl paraffins. Isopentane, although adsorbed along with the mono-methyl paraffins, is preferentially eluted from the adsorber and recovered as an adsorption effluent.

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Journal of Chromatography, 316 (1984) 333-341.

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