Adsorbed monomolecular film and method of manufacturing the same

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428421, 428447, 428448, B32B 700

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052252744

ABSTRACT:
The invention seeks to provide a method of forming a monomolecular film of fluorine-containing molecules on a substrate surface such that the film has a uniform thickness with minimal surface irregularities and is substantially pin hole free. The invention also provides for a substrate obtained by using the same method which has excellent water- and oil-repelling, anti-fogging, and anti-contaminating properties. The monomolecular film is formed on the substrate surface either directly or via a given protective film. The monomolecular film coating is characterized by a plurality of different chlorosilane-based surface active materials which are different in molecular length and have a fluorine group. The surface irregularities of the film are generally confined to the molecular level.

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patent: 4992300 (1991-02-01), Ogawa et al.
World Patents Index Latest, Derwent Publications Ltd., London, GB; AN 86-065417 & JP-A-61 016 910 (Hitachi Cable KK), Jan. 24, 1986 (abstract).
Japanese Journal of Applied Physics vol. 26, No. 10, 10 Oct. 1987, pp. 1622-1624, Nakanishi et al., Fabrication of Polar Structures by Use of LB Technique.
Roberts, G., Langmuir-Blodgett Films, 1 May 1990, Plenum Press, NY, paragraph 2.2.4, pp. 26-27.
Thin Solid Films, vol. 178, No. 1, 1 Nov. 1989, Lausanne, CH, pp. 327-340, Palacin S., Supermolecular Engineering in Langmuir-Blodgett Films.
Thin Solid Films, vol. 179, No. 1, 11 Nov. 1989, Lausanne CH, pp. 429-432, M-A Sato et al., Langmuir-Blodgett films of polyalkylthiophene-poly(isobutyl methacrylate) mixed polymers and their optical and electrical . . . .

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