Adhesive comprising reaction product of gamma-isocyanatopropyltr

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525446, C08L 6702, C08L 6700

Patent

active

044080212

ABSTRACT:
A water-activatable adhesive useful for adhering a solar film, polyester (polyethylene terephthalate) film, to glass. The adhesive comprises the reacted product of (A) gamma-isocyanatopropyltriethoxy silane, containing a free isocyanate (NCO) group, and (B) a thermoplastic polyester formed by reacting (i) a dibasic acid selected from the group consisting of terephthalic acid, isophthalic acid and hexahydrophthalic acid, and mixtures thereof, with (ii) a polymethylene glycol of the formula HO(CH.sub.2).sub.x OH where x is an integer from 2 to 10, neopentyl glycol and glycerin, and mixtures thereof, and (iii) an aliphatic dibasic acid selected from the group consisting of those having the formula HOOC(CH.sub.2).sub.n COOH where n is an integer from 1 to 8, and mixtures of such acids, whereby substantially no free NCO remains in the adhesive.
Solar film is used for absorbing and/or reflecting solar radiation. Solar film can be a single sheet of polyester dyed sufficiently to absorb the glare of bright sunlight, or it can be a single sheet of polyester, on one side of which a reflective metal (most often aluminum) is deposited in an amount which can be totally reflective or in an amount which still allows visible light transmission and over which a protective coating is deposited, or it can be a laminated structure of the reflective film adhered to a clear or dyed polyester film by which means the reflective metal is sandwiched between two layers of polyester film, or it can be a laminated structure of a reflective film to a polyolefin film.

REFERENCES:
patent: 3309261 (1967-03-01), Schiller et al.
patent: 3886226 (1975-05-01), Asai et al.
patent: 4206299 (1980-06-01), Yamazaki et al.

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