Adhesion promoted block copolyester composition with multi-funct

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260 457P, 260 4595R, 260 26, 260 27R, 260873, 260 459D, 528273, C08L 6702

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041567021

ABSTRACT:
Thermoplastic segmented copolyester elastomer consisting essentially of a multiplicity of recurring short chain ester units and long chain ester units joined through ester linkages, said short chain ester units amounting to 15 to 75 percent by weight of said copolyester and being derived from dicarboxylic acid such as an aromatic acid, e.g., terephthalic acid or a mixture of terephthalic acid and isophthalic acid, and an organic diol such as butanediol, and said long chain ester units amounting to 25 to 85 percent by weight of said copolyester and being derived from dicarboxylic acid such as an aromatic acid, e.g., terephthalic acid, or a mixture of terephthalic and isophthalic acids, and a long chain glycol such as polytetramethylene ether glycol, said copolyester having a melt index of less than 150 and a melting point of at least 90.degree. C., modified with 0.75 to 20 parts by weight, per 100 parts by weight of elastomer, of a multi-functional carboxylic compound taken from the group consisting of aromatic and aliphatic anhydrides having at least two anhydride groups. The modified elastomer possesses improved adhesion particularly at high temperatures and under high applied stress. A useful adhesive composition comprises (A) 1 to 99 percent by weight of the segmented copolyester elastomer, and (B) 99 to 1 percent by weight of a compatible low molecular weight thermoplastic resin. The adhesive composition can contain stabilizers as well as other ingredients.

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