Additive for producing a positive active material for...

Colloid systems and wetting agents; subcombinations thereof; pro – Continuous liquid or supercritical phase: colloid systems;... – Aqueous continuous liquid phase and discontinuous phase...

Reexamination Certificate

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C252S182110, C423S266000, C423S267000, C423S559000, C428S404000

Reexamination Certificate

active

07091250

ABSTRACT:
The present invention is an additive for producing a positive active material for lead-acid storage batteries on the basis of finely divided tetrabasic lead sulfate. The additive contains a tetrabasic lead sulfate of an average particle size less than about 3 μm as well as finely divided hydrophobic silicic acid for preventing agglomeration of the particles of the tetrabasic lead sulfate. During maturation, this additive ensures the formation of the structure of a tetrabasic lead sulfate crystal with a very narrow bandwidth of crystal sizes and a very homogeneous distribution. In the subsequent electrochemical formation to lead oxide, this leads to particularly efficient lead-acid storage batteries. Furthermore, the invention relates to a method of making the additive according to the invention as well as its advantageous use in the positive material for the maturation and drying of plates in the production of lead-acid storage batteries.

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Derwent abstract ACC-No.: 1999-156278, of FR 2767224A1.
JPO abstract of JP 1-200558A.
USPTO obtained Derwent machine assisted translation of JP 5-242877A, Mukoya et al. (Sep. 21, 1993).
USPTO obtained translation of JP 63-6743 (Jan. 12, 1988).
USPTO obtained translation of DE 3532697A1 (19870402).
J. A. Wertz et al, Development of Advanced Lead Acid Batteries for Electric Vehicles. The Use of Additives to Increase Performance and Extend Life, Part I, AGM Cells, pp. 189-195, IEEE (1999).
K. McGregor, Active-Material Additives For High-Rate Lead/Acid Batteries: Have There Been Any Positive Advances?, Journal of Power Sources 59, pp. 31-43, (1996).
H. Dietz et al., The Effect of Additives on the Positive Lead-Acid Battery Electrode, Journal of Power Sources 14, pp. 305-319 (1985).
International Search Report dated Aug. 31, 2004 for International Appl. No. PCT/EP03/14590.
German Search Report, dated May 23, 2003, for corresponding application DE 102 61 049.5.

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