Additive for enhancing the performance of electrochemical cells

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

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C429S199000, C429S329000, C429S332000, C252S519200

Reexamination Certificate

active

10625686

ABSTRACT:
A lithium battery includes an electrolyte comprised of a non-aqueous solvent, and a salt mixture. The salt mixture includes an alkali metal electrolyte salt and an additive salt having an anion of a mixed anhydride of oxalic acid and boric acid. Specific additive salts include lithium bis(oxalato) borate and lithium oxalyldifluoroborate. Particular electrolyte salts comprise LiPF6and LiBF4. The additive salt is present in an amount of 0.1–60 mole percent of the total of the additive salt and electrolyte salt content of the electrolyte. Also disclosed is a method for enhancing the performance characteristics of a lithium battery through the use of the electrolyte composition. Also disclosed is the compound lithium oxalyldifluoroborate.

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patent: 6506516 (2003-01-01), Wietelmann et al.
patent: 6783896 (2004-08-01), Tsujioka et al.
Jow et al. “Nonaqueous Electrolytes for Wide Temperature Range Operations of Li-ion Cells” 11th International Meeting on Lithium Batteries, Monterey, CA (Jun. 23-28, 2002).
Xu et al. “LiBOB as Salt for Lithium-Ion Batteries” Electrochemical and Solid-State Letters, 5 (1) A26-A29 (2002).
Xu et al. “LiBOB and Its Derivatives” Electrochemical and Solid-State Letters, 4 (1) E1-E4 (2001).
Jow et al. “LiBOB as an Electrolyte Salt for Lithium Ion Cells” The 42nd Battery Symposium in Japan, Nov. 21-23, 2001, Yokahama, Japan.

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