Addition polymers derived from norbornene-functional monomers an

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

526 82, 526161, 526164, 526169, 526177, 526178, 526179, 526281, 526282, 526283, 526308, C08F 480, C08F 476, C08F 478, C08F 1000

Patent

active

057418691

ABSTRACT:
Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.

REFERENCES:
patent: 2721189 (1955-10-01), Anderson et al.
patent: 3330815 (1967-07-01), McKeon
patent: 4599391 (1986-07-01), Yamamoto et al.
patent: 4599931 (1986-07-01), Yamamoto
patent: 4959436 (1990-09-01), Cozewith
patent: 5087677 (1992-02-01), Brekner
G. Odian, "Principles of Polymerization," 3rd Ed (1991) 369-370, Wiley (New York).
"Preparation and Reactivity Studies of Highly Versatile, Nickel-Based Polymerization Catalyst System" by T. J. Deming and B.M. Novak, Macromolecules 1993, 26, 7089-7091.
"Comprehensive Organometallic Chemistry" by Geoffrey Wilkinson et al, Chapter Ziegler-Natta Catalysis by Galens et al, p. 484 et seq.
"The Organic Chemistry of Nickel" by P. W. Jolly and G. Wilke, vol. 1 Academic Press, New York, p. 352 (1974).
J. of Polymer Science, Part C 1b, p. 2525 (1967) by L. Porri, G. Natta, and M. C. Gallazzi.
"Copolymers of Ethylene with Bicyclic Dienes" by Schnecko et al Die Angewandte Makromolekulare Chemie, 20, 141-152 (1971).
Chim. Ind. (Milan) by L. Porri, G. Natta, and M. C. Gallazzi, 46 428 (1964).
Stud. Surf. Sci. Catal. 56 425 (1990) by W. Kaminsky et al.
Makromol. Chem. Macromol. Symp. 47 83 (1991) by W. Kaminsky et al.
J. Mol. Cat. 74 109 (1992) by W. Kaminsky et al.
Shokubai 33 536 (1991) by W. Kaminsky.
"Polypropylene and Other Polyolefins Polymerization and Characterization" by Ser van der Ven-Studies in Polymer Science-7, Elsevier (1990), pp. 71-84.
J. of Organometal. Chemistry by A. Sen, T. Lai, and R. Thomas 358 567-568 (1988).
Makromol. Chem. Rapid Commun. 12, 255-259 (1991) by C. Mehler and W. Risse, "The Pd (II) Catalyzed Polymerization of Norbornene".
Makromol. Chem., Rapid Commun. 13, 455-459 (1992) by C. Mehler and W. Risse, "The PD (II) Catalyzed Polymerization of Norbornene Derivatives".
"Olefin Metathesis" by K. J. Ivin, Academic Press (1983).
J. Polym. Sci, Polym. Chem., by U. Klabunde et al 25 1989 (1987).
"Homogeneous Catalysis: The Applications and Chemistry of Catalysis by Soluble Transition Metal Complexes" by G. W. Parshall and Ittel, pp. 70-71 (1992).
Makromol. Chem. 139 73 (1970) by R. Sakata et al, "Effect of Unsaturated Hydrocarbons on the Polymerization of Butadiene etc.".
"Synthesis and Characterization of poly(5-alkyl-2-norbornene) by Cationic Polymerization" by T. Sagane et al. Macromol. Chem. 194 37-52 (1993).
"Zietschrift fur Kristallographie" 201 287-289 (1992) by R. Kempe and J. Sieler.
Encyclopedia of Polymer Science and Engineering, 2nd Edition vol. 2, John Wiley & Sons (1985).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Addition polymers derived from norbornene-functional monomers an does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Addition polymers derived from norbornene-functional monomers an, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Addition polymers derived from norbornene-functional monomers an will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2058441

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.