Addition of organophosphonates for size control of wet calcium-b

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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4232422, 4232427, 42324308, 423555, 4235192, C01B 1700, C01B 1720, C01B 1722

Patent

active

052466795

ABSTRACT:
A process for producing large, regularly-shaped crystalline calcium sulfite solids in a wet calcium-based flue gas desulfurization system is provided. A chemical crystal modifier, preferably an organophosphonate, is added to the calcium sulfite-containing solids slurry produced by the FGD process under inhibited oxidation conditions at an addition level which promotes the formation of large, regular calcium sulfite crystals that are easily dewatered.

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