Addition of chlorine compound to Ziegler polymerization process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252429B, 526137, 526144, 526351, C08F 200, C08F 214

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active

042672929

ABSTRACT:
A process for polymerizing alpha-olefins in the presence of a Ziegler-type catalyst wherein at least one of dichloroethane, dichloropropane and chlorine gas is added to the process after the polymerization has been initiated. This invention is especially useful when the olefin is propylene and the catalyst is a titanium trichloride complex.

REFERENCES:
patent: 3072630 (1963-01-01), De Jong et al.
patent: 3326872 (1967-06-01), Weber et al.
patent: 3349064 (1967-10-01), Gumboldt et al.
patent: 3462399 (1969-08-01), Matthews
patent: 3692712 (1972-09-01), Crouch
patent: 3957910 (1976-05-01), Van Den Berg

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