Addition of aldehydes to organic compounds having a carbon-hydro

Details Addition of aldehydes to organic compounds having a carbon-hydro Addition of aldehydes to organic compounds having a carbon-hydro

1985-02-28

1986-04-08

Torrence, Dolph H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Nitriles

568705, 568709, 568710, 568711, 568712, 568713, 544 49, 544215, 546176, 546180, 546246, 546330, 546334, 548205, 548341, 548503, 548561, 548566, 549 58, 549 75, 549467, 549491, 562434, 562437, 562438, 562561, 562567, 564 87, 564 95, 564 96, 564441, 564503, 568704, C07C12175, C07C12134, C07C 7918, C07C 7922

Patent

active

045811784

ABSTRACT:
Low valent transition metal complexes containing small cone angle phosphine or arsine ligands efficiently catalyze addition of aldehydes to compounds or groups having a C--H bond activated by a nitro or nitrile group, to provide nitroalcohols or cyanohydrins, respectively.

REFERENCES:
patent: 3564062 (1971-02-01), Tindall
patent: 3723546 (1973-03-01), Bachman et al.
Cope et al., eds. Organic Reactions, vol. 15, pp. 204-273 (Wiley, New York, 1967).
Baer et al., "Activating and Directing Effects of the Nitro Group in Aliphatic Systems", in Feuer et al., Eds., The Chemistry of the Nitro and Nitroso Groups, pp. 75-187 (Wiley-Interscience, New York, 1970).
Iwata et al., Bull. Chem. Soc. Jpn. 49:1369 (1976).
Irie et al., Bull. Chem. Soc. Jpn. 53:1366 (1980).
Irie et al., Bull. Chem. Soc. Jpn. 54:1195 (1981).
Watanabe et al., Bull. Chem. Soc. Jpn. 55:3208 (1982).
Irie, Nippon Kagaku Kaishi 1983(1):150 (1983) (CA 98:160318m).

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