Adamantane derivatives and process for producing them

Details Adamantane derivatives and process for producing them Adamantane derivatives and process for producing them

2007-07-24

2007-07-24

McKenzie, Thomas (Department: 1625)

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C548S545000, C548S549000, C548S551000, C548S552000, C548S152000, C562S499000, C562S502000, C562S501000, C564S457000, C564S458000, C502S167000

Reissue Patent

active

10830494

ABSTRACT:
In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the formula (2):wherein R1and R2independently represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group; or R1and R2may bond together to form a double bond or an aromatic or non-aromatic ring; Y is O or OH and n=1 to 3;or the imide compound and a co-catalyst (e.g., a transition metal compound), an adamantane derivative having a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is oxidized with oxygen. According to the above method, an adamantane derivative having a hydroxyl group together with a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is efficiently obtained.

REFERENCES:
patent: 3356741 (1967-12-01), Schneider
patent: 3450775 (1969-06-01), Schneider
patent: 3594427 (1971-07-01), Moore
patent: 3753950 (1973-08-01), Thompson
patent: 3760020 (1973-09-01), Moore
patent: 3832332 (1974-08-01), Thompson
patent: 3994960 (1976-11-01), Yamazaki et al.
patent: 4476060 (1984-10-01), Gilbert
patent: 5030739 (1991-07-01), Foricher et al.
patent: 5958821 (1999-09-01), Ishii et al.
patent: 6207342 (2001-03-01), Takechi et al.
patent: 6235851 (2001-05-01), Ishii et al.
patent: 6468487 (2002-10-01), Ishii et al.
patent: 4216621 (1942-09-01), None
patent: 4226792 (1942-12-01), None
patent: 43-937 (1968-01-01), None
patent: 4412891 (1969-06-01), None
patent: 4628419 (1971-08-01), None
patent: 5021090 (1975-03-01), None
patent: 63307844 (1988-12-01), None
patent: 2196744 (1990-08-01), None
patent: 838909 (1996-02-01), None
patent: WO9640641 (1996-12-01), None
Kontani et al, A New combined Oxidizing Reagent System, Nov. 1985, Chem. & Pharm. Bulletin, 33 (11), p. 4680-4684.
G.R. Newkome et al., J. Org. Chem, vol. 57, No. 1, 1992, pp. 358-362.
A. Bashir-Hashemi et al., Tetrahedron Letters, vol. 36, No. 8, 1995, pp. 1233-1236.
R.E. Moore et al., J. Org. Chem., vol. 43, No. 26, 1978, pp. 4978-4980.
I.N. Butenko et al., Synthetic Communications, vol. 14, No. 2, 1984, pp. 113-119.
S. Grimme et al., Chem. Ber, 127, (1994), pp. 2081-2088.
Dolgopolpva, T.N., et al. “Thin-layer chromatography of oxygen-containing derivatives of adamantane” Zh. Anal. Khim., (1989),44(9), p. 1689-1690.
Tadashi Sasaki et al., “Synthesis of adamantane derivatives” J. Org. Chem., (1982), 47, p. 3219-3224.
Kozlovskii, Ya. B. et al., (1989), 25(6), p. 1222-1226.
Vishnevskii, E.N. et al. (1996), 32(7), p. 1030-1035.
Kontani, et al., A New Combined Oxidizing Reagent System, Nov. 1985, Chem. & Pharm. Bulletin, 33(11), p. 4680-4684.

Affiliated with

Also associated with

Rating

Adamantane derivatives and process for producing them does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Adamantane derivatives and process for producing them, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Adamantane derivatives and process for producing them will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-3762878