Adamantane catalyzed paraffin-olefin alkylation

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By condensation of a paraffin molecule with an olefin-acting...

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585725, 585726, 585727, 585728, 585729, 585730, 585731, 585732, 585721, 585723, C07C 258, C07C 260, C07C 262

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043574815

ABSTRACT:
A process is described for paraffin-olefin alkylation under strong acid conditions in which an adamantane hydrocarbon is used to substantially increase the reaction rate of the alkylation.

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patent: 4229611 (1980-10-01), Kramer
"Industrial Laboratory Alkylation" edited by Lyle F. Albright and Arthur R. Goldsby, ACS Symposium Series 55, published Washington, D.C., 1977, Chapter One, Alkylation Studies by George M. Kramer.
J. Org. Chem. 44, pp. 2619-2624 (1979), by D. Mirda, D. Rapp and G. M. Kramer.
J. Amer. Chem. Soc. 98, pp. 5864-5870, (1976), by P. Van Pelt and H. M. Buck.

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