Acyloxylation of alkylaromatic compounds with palladium-tin cata

Details Acyloxylation of alkylaromatic compounds with palladium-tin cata Acyloxylation of alkylaromatic compounds with palladium-tin cata

1991-11-06

1993-04-27

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

502339, 560254, 560103, 560106, C07C 2710

Patent

active

052064239

ABSTRACT:
This invention provides process embodiments for acyloxylation of C.sub.1 -C.sub.4 alkylaromatic compounds to produce alpha-acyloxy C.sub.1 -C.sub.4 alkyl-substituted aromatic compounds, utilizing a palladium-tin catalyst which exhibits efficient oxidation selectivity and oxidation rate stability.
Toluene is acetoxylated to benzyl acetate and benzylidene diacetate.

REFERENCES:
CA 88 (14): 95346w, 1977.

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