Acyloxy-N,N'-diacylmalonamides and methods for their preparation

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal


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2604045, 560 11, 560 43, 560 45, 560 47, 560 61, 560 74, 560110, 560111, 560100, 560107, 560149, 560156, 560157, 560179, 560185, 560187, 560227, 560229, 560226, 560251, 560254, 560255, 560105, 560228, C07C14390, C11D 128, C09F 500




.alpha.-Acyloxy-N,N'-diacylmalonamides of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different and are hydrogen, straight chain or branched alkyl radicals having from one to eleven carbon atoms, or hydrocarbon radicals with six to twelve carbon atoms and comprising at least one aromatic ring, are novel compounds prepared by the action of a mixture of carboxylic acids R.sub.3 COOH and R.sub.4 COOH upon an .alpha.-acyloxymalononitrile, R.sub.1 COO--C(CN).sub.2 --R.sub.2, in the presence of an acid catalyst and are useful as intermediates in organic synthesis and low temperature activators in bleaching or scouring compositions.

patent: 808748 (1906-01-01), Hofmann
Cossi et al., Chemical Abstracts, 135681d, vol. 78 (1973).
Ho Chemical Abstracts vol. 82:85423f (1975).


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