Acylation of aromatics

Details Acylation of aromatics Acylation of aromatics

1988-05-25

1990-01-23

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568323, 562460, C07C 4546

Patent

active

048959847

ABSTRACT:
Aromatics are acylated by the Friedel-Crafts method by carrying out the acylation in the presence of metalalkyls or metalalkyl halides of metals or semimetals of main groups two to five and/or of metals of subgroups two or four of the Periodic Table.

REFERENCES:
patent: 2004069 (1935-06-01), Bruson et al.
patent: 2587540 (1952-02-01), Shaver
patent: 3154585 (1964-10-01), Flanagan
patent: 4087458 (1978-03-01), Emori et al.
patent: 4310705 (1982-01-01), Nissen et al.
Sneider et al., Tetrahedron, vol. 37, pp. 3927 to 3934 (1981).
Sneider et al., J. Org. Chem., vol. 47, pp. 5393-5395 (1982).
Reinheckel et al., J. Organometalic Chemistry, vol. 13, pp. 45-51 (1968).
Houben-Weyl, Methoden der Org. Chem., vol. VII/2a, 1973, pp. 15-39 and 311-325.
Freidel-Crafts and Related Reactions, vol. I, p. 207 and vol. III, Part I, pp. 550-553.

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