Stock material or miscellaneous articles – Hollow or container type article – Glass – ceramic – or sintered – fused – fired – or calcined metal...
Reexamination Certificate
2002-01-08
2004-08-31
Pyon, Harold (Department: 1772)
Stock material or miscellaneous articles
Hollow or container type article
Glass, ceramic, or sintered, fused, fired, or calcined metal...
C428S034100, C060S257000, C060S260000, C060S267000
Reexamination Certificate
active
06783824
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to actively-cooled tubular shell structures for high-temperature applications having a plurality of cooling channels formed between the inner wall and outer wall of the structure wherein the structure is fabricated from fiber-reinforced ceramic matrix composite materials and methods of producing same.
BACKGROUND OF THE INVENTION
Performance of advanced chemical rocket technology is limited, for the most part, by the availability of high-temperature structural engineering materials. Greater performance and efficiency in liquid rocket propulsion systems can be gained by operating at higher combustion temperatures and higher working pressures resulting from highly energetic propellant mixture ratios (oxidizer/fuel). However, propellant mixtures are typically “tamed” to off-optimum conditions in order not to exceed the temperature limitations of the thrust chamber and nozzle materials.
A considerable amount of heat is transferred in all designs of rocket engines. The principle objective of high-temperature rocket design is to safely limit the heat transfer to the materials in critical hot sections such as the injector, combustion chamber, throat, and nozzle. A failure would impair the satisfactory operation of the rocket propulsion system or the flight vehicle being propelled. The walls have to be maintained sufficiently cool so that wall temperatures do not exceed their safe allowable operating limit. Erosion, usually the result of combined oxidation and chemical interaction with the hot combustion gases, should not damage the walls, and the walls should be capable of withstanding the extreme thermal shock caused by the sudden onset of a high heat flux from combustion ignition. The materials comprising the thrust chamber devices must also be capable of resisting the thermal stresses induced by the heat transfer and thermal gradients.
There are two general cooling methods commonly used today in the design of liquid propellant rocket engine devices. Those devices that reach thermal equilibrium during operation typically operate for long durations and are usually either actively-cooled (e.g., bipropellants) or radiation cooled (e.g., monopropellants).
Actively-cooled liquid propellant thrust chambers have provisions for cooling some or all of the components in contact with the hot combustion gases, such as the chamber walls, nozzle walls and injector faces. A cooling jacket or cooling coil often consists of separate inner and outer walls or a bundled assembly of continuous, contoured tubes. The inner wall confines the combustion gases, and the space between the inner and outer walls serves as the coolant passage. The axial or helical passages in liquid propellant rocket thrust chambers are often of complex cross-section. The nozzle throat region is usually the location that sustains the greatest heat transfer intensity and is therefore the most difficult to cool. For this reason the cooling jacket is often designed so that the coolant velocity is highest at the critical regions by restricting the coolant passage cross-section and so that the coolant enters the jacket at or near the nozzle.
Regenerative cooling is a form of active cooling and is used for engines where one of the propellant constituents is circulated through cooling passages around the thrust chamber prior to injection and burning of the propellant in the combustion chamber. Regenerative cooling in bipropellant engines uses either the fuel or oxidizer as the cooling fluid. Therefore, the thermal energy absorbed by the coolant is not wasted as it augments the initial energy content of the propellant prior to injection, thereby increasing the exhaust velocity and propulsive performance.
Radiation cooling is typically used in monopropellant thrust chambers, some gas generators and for nozzle exhaust sections. Radiation cooling is a simple, lightweight cooling method, which is commonly employed in low-temperature rocket engines, such as hydrazine (monopropellant) spacecraft maneuver and attitude control systems, where the maximum chamber temperature is only about 650° C. Refractory metals such as molybdenum, tantalum, tungsten, and niobium have been used in radiation cooled thrust chambers requiring increased operating temperatures up to 1650° C. Refractory metals are, however, difficult to fabricate and some suffer from hydrogen embrittlement degradation; others oxidize readily and thus require protective surface coatings to function reliably; all are weight inefficient due to their very high specific gravities. Radiation cooled thrust chambers generally have to protrude beyond the outer skin of the flight vehicle to permit satisfactory radiative heat rejection.
In general, ceramics have superior high-temperature strength and stiffness, and lower density than metallic materials. The principal disadvantages of ceramics as structural materials are their low failure strain, low fracture toughness and catastrophic brittle failure characteristics. Because of these inherent limitations, monolithic ceramics lack the properties of reliability and durability that are necessary for structural design acceptance. However, the emerging technology of fiber-reinforced ceramics, or ceramic matrix composites is one promising solution for overcoming the reliability and durability problems associated with monolithic ceramics. By incorporating high strength, relatively high modulus fibers into brittle ceramic matrices, combined high strength and high toughness composite materials can be obtained. Successfully manufactured ceramic matrix composites exhibit a high degree of non-linear stress-strain behavior with ultimate strengths, failure strains and fracture toughnesses that are substantially greater than that of the unreinforced matrix.
In order to exploit the benefits of fiber reinforcement in brittle ceramic matrices, it is well recognized that a relatively weak fiber/matrix interfacial bond strength is essential for preventing catastrophic failure from propagating matrix cracks. The interface must provide sufficient fiber/matrix bonding for effective load transfer, but must be weak enough to debond and slip in the wake of matrix cracking, leaving the fibers to bridge the cracks and support the far-field applied load. Fiber-reinforced ceramic matrix composites with very high fiber/matrix interfacial bond strengths (usually the result of chemical interaction during manufacture) exhibit brittle failure characteristics similar to that of unreinforced monolithic ceramics by allowing matrix cracks to freely propagate directly through the reinforcing fibers. Conversely, by reducing the interfacial bond strength, the fiber and matrix are able to debond and slip promoting the arrest and/or diversion of propagating matrix cracks at/or around the reinforcing fiber. Since crack inhibition/fracture toughness enhancement is the primary advantage of fiber-reinforced ceramic matrix composites, properly engineered fiber coating systems are thus key to the structural performance of these materials. Control of interfacial bonding characteristics between the fiber and matrix following manufacture and during service is typically provided by the use of applied fiber coatings.
Fiber-reinforced ceramic matrix composites produced by the chemical vapor infiltration (CVI) process are a particularly promising class of engineered high-temperature structural materials, which are now commercially available. The principal advantage of the CVI process approach for fabricating ceramic matrix composites as compared to other manufacturing methods (e.g., reaction bonding, hot-pressing, melt infiltration, or polymer impregnation/pyrolysis) is the ability to infiltrate and densify geometrically complex, multidirectional fibrous preforms to near-net-shape with a ceramic matrix of high purity and controllable stoichiometry without chemically, thermally or mechanically damaging the relatively fragile reinforcing fibers. In addition, because it is a relatively low temperature manufacturing process, high purity refractory matr
Egan Brian P.
Fischer Morland C.
Hyper-Therm High-Temperature Composites, Inc.
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