Activation of zeolites using hydrate of trivalent metal fluoride

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – Gallium containing

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502 85, B01J 3700, B01J 2906

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active

051262967

ABSTRACT:
A method for enhancing the activity of a porous crystalline zeolite having a framework silica-to-alumina mole ratio of 25 or more which comprises contacting the zeolite with a solution comprising a hydrate of trivalent metal fluoride in aqueous media under conditions sufficient to cause incorporation of said metal in the framework of said zeolite.

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Brauer, G. (Ed.), Handbook of Preparative Inorganic Chemistry, vol. 1, 2nd. Ed., p. 225, Academic Press, N.Y., 1963.
Chang et al.., "Aluminum Insertion into High Silica Zeolite Frameworks. 1. Reaction with Aluminum Halides, " J. Am. Chem. Soc., 1984, 106, 8143-81, p. 8145.
Yu. A. Buslaev, S. P. Petrosyants: The Composition of Fluorine Complexes of Aluminum and Fluosilicic Acid in Aqueous Solutions, Jul. 17, 1978.

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