Acrylic synthetic fiber and process for preparation thereof

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Rod – strand – filament or fiber

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428376, 428400, 428397, 264 41, 264 49, 264 458, 264 459, D02G 300

Patent

active

053447115

ABSTRACT:
An acrylic synthetic fiber having in the transverse section thereof many openings having an indeterminate shape and a size of 0.1 to 1.6 .mu.m, wherein in the interior of the fiber, each opening forms a vein-like or straw-like void extending substantially in parallel to the longitudinal axis of the fiber and having a length of at least 60 .mu.m. This acrylic fiber is prepared by a) dissolving in a suitable solvent an acrylic polymer comprising at least 60 weight % of an acrylonitrile unit and 5 to 20 weight %, based on the weight of the acrylic polymer, of a polyalkylene glycol having a number average molecular weight of 5,000 to 50,000, b) aging the formed spinning solution for at least 4 hours, and c) extruding the spinning solution into a coagulating medium. The acrylic fiber is useful, e.g., as a frictional material comprising (a) a pulpy material made from the acrylic fiber, (b) a resin and (c) a filler.

REFERENCES:
patent: 2788563 (1957-04-01), Stucklik et al.
patent: 3802954 (1974-04-01), Orito et al.
patent: 4346146 (1982-08-01), Kondo et al.
patent: 4347203 (1982-08-01), Mimura et al.
patent: 4643946 (1987-02-01), Brauer et al.
patent: 4663232 (1987-05-01), Kamide et al.

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