Acrylic modifiers for polycarbonamides

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260 23AR, 260 237N, 260 318M, 260 318N, 260 318DR, 260 37N, 260 4213, 260 4221, 260 4222, 260 4229, 260 4237, 260 457P, 260857D, 260857G, 260877, 260 458R, 260 4585A, 260 4595R, C08L 3102

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active

041488466

ABSTRACT:
An impact resistant nitrogenous polymer comprises a multiphase amine-reactive moiety-containing polymer grafted to a polycarbonamide containing recurring amide linkages as anintegral part of the polymer chain; the grafting, by reaction of an amine-reactive moiety of the polymer with an amine end group of the polycarbonamide. Preferably the amine-reactive moiety-containing polymer is a multiphase carboxylic acid-containing polymer comprising (A) a first elastomer phase that is preferably polymerized from monomers comprising: 50 to 99.9 parts by weight alkyl acrylate wherein the alkyl group contains 1 to 15 carbon atoms, butadiene or substituted butadiene; 0 to 40 parts by weight of other ethylenically unsaturated monomers; 0 to 5 parts by weight of a polyethylenically unsaturated crosslinking monomer; and 0 to 5 parts by weight of a graft-linking monomer; and (B) a final rigid thermoplastic stage containing amine-reactive carboxylic acid groups and polymerized from monomers comprising, 1 to 50 parts by weight of a copolymerizable carboxylic acid; 50 to 99 parts by weight of a member selected from the group consisting of alkyl methacrylates, styrenes, acrylonitrile, methacrylonitrile and olefins that, when homopolymerized, form polymers having a heat distortion temperature greater than about 20.degree. C.; 0 to 49 parts by weight of another acrylic monomer; and 0 to 40 parts of another copolymerizable ethylenically unsaturated monomer. The impact resistant nitrogenous polymer is characterized by superior hot strength that renders the polymer extrudable, blow moldable, and injection moldable.

REFERENCES:
patent: 3244655 (1966-04-01), Sullivan et al.
patent: 3793402 (1974-02-01), Owens

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